Infrastructure development has been a priority area since the Belt and Road Initiative (BRI) was proposed. This paper uses the generalized method of moments (GMM) to analyze the relationship between the green logistics, environment and economic growth based on panel data of countries along the BRI from 2007 to 2018. It is found that fossil fuels are the core of logistics operation activities, and the more fossil fuels are used, the more detrimental to the sustainable development of the environment. "The green logistics is negatively correlated with fossil fuel energy consumption and carbon emissions per capita in countries along the Belt and Road. At the same time, the green logistics can also bring more export opportunities for these countries and increase the national income per capita. The development of the green logistics is of great significance to the countries' environment and sustainable economic development along the Belt and Road.