This article represents the data set of micro porous core photonic crystal fiber based chemical sensor. The suggested structure is folded cladding porous shaped with circular air hole. Here is investigated four distinctive parameters including relative sensitivity, confinement loss, numerical aperture (NA), and effective area (Aeff). The numerical outcomes are computed over the E+S+C+L+U communication band. The useable sensed chemicals are methanol, ethanol, propanol, butanol, and pentanol whose are lies in the alcohol series (Paul et al., 2017) [1]. Furthermore, V-parameter (V), Marcuse spot size (MSS), and beam divergence (BD) are also investigated rigorously. All examined results have been obtained using finite element method based simulation software COMSOL Multiphysics 4.2 versions with anisotropic circular perfectly matched layer (A-CPML). The proposed PCF shows the high NA from 0.35 to 0.36; the low CL from ~10^–11 to ~10⁻⁷ dB/m; the high A_eff from 5.50 to 5.66 µm²; the MSS from 1.0 to 1.08 µm; the BD from 0.43 to 0.46 rad at the controlling wavelength λ = 1.55 µm for employing alcohol series respectively.